The natural background concentration of an element is the concentration that would exist in the absence of human input. Some elements exist naturally over a wide range of concentrations and it is important to know whether the amount present at a site is a result of human contamination or natural processes.
Scientists use background concentrations for two main reasons:
Background soil concentrations are also specifically mentioned in the National Environmental Standard for Assessing and Managing Contaminants in Soil to Protect Human Health (2012) which is implemented by district and city councils.
The most common method of estimating natural background values is sampling soil at native reserve sites where no direct human use has occurred (i.e. well removed from urban areas and fertilised land). This approach is applicable in New Zealand where we have experienced negligible atmospheric inputs of trace elements to soil.
Soil samples from 38 sites have been chosen to represent background concentrations for the Waikato region. Their soil types represent the most common in our region but do not include peat soils as these have quite different properties.
Each sample was analysed for acid recoverable trace element content (except for total fluorine) and the 95th percentile has been calculated for each element to give an upper limit for the natural range of concentrations.
Some compounds relevant to contaminated land investigations (e.g. DDT, PCP, Dieldrin and dioxin) are not naturally occurring, so any detection of these compounds indicates a human input. Small amounts of hydrocarbon compounds (e.g. BaP, PAHs and TPH) may be present naturally due to natural bush fires, volcanic eruptions and decaying organic matter but, as these are extremely variable, background data is not presented for these compounds.
|Element||Symbol||95% upper limit for background (mg/kg)|
Kim ND, Taylor MD (2009) Trace element monitoring. In: Land Monitoring Forum. Land and Soil Monitoring: A guide for SoE and regional council reporting. Hamilton: Land Monitoring Forum. pp 117–178. Available at http://www.envirolink.govt.nz/assets/PageFiles/31/Land%20and%20soil%20monitoring__A_guide_for_SoE%20and%20regional%20council%20reporting.PDF(external link)
Kim, N. (2005). Cadmium Accumulation in Waikato Soils. Waikato Regional Council Technical report TR 2005/51, Hamilton New Zealand. Available at http://www.waikatoregion.govt.nz/tr200551/(external link)
McLaughlin M J, Smolders E (2001) Background zinc concentrations in soil affect the zinc sensitivity of soil microbial processes—a rationale for a metalloregion approach to risk assessments. Environ. Toxicol. Chem. 20: 2639-2643.
Taylor, M. (2015). Soil quality monitoring in the Waikato region 2012. Waikato Regional Council Technical Report TR 2015/02. Available at http://www.waikatoregion.govt.nz/TR201502/(external link)
Taylor MD, Kim ND (2009) Dealumination as a mechanism for increased acid recoverable aluminium in Waikato mineral soils. Australian Journal of Soil Research. 47, pp 828-838.
Taylor MD, Cavanagh J, Curran-Cournane F, Gray C, Drewry J, Guinto D, Cuff JR, Briggs R, Kim ND, Schnug E (2014) Background concentrations of major and trace elements in NZ soils by XRF and acid extraction compared to World literature. New Zealand Soil Science Society conference “Soil science for future generations”, Hamilton, New Zealand, December 1-4, 2014. Available at https://www.researchgate.net/publication/281102165_Background_concentrations_of_major_and_trace_elements_in_NZ_soils_by_XRF_and_acid_extraction_compared_to_World_literature(external link)